CH6503 - CHEMICAL ENGINEERING THERMODYNAMICS II (Syllabus) 2013-regulation Anna University

CH6503

CHEMICAL ENGINEERING THERMODYNAMICS II

 LPTC

3 1 0 4

OBJECTIVES:
The enable the students to understand the behavior of fluids under PVT conditions and also apply them for practical purpose.

UNIT I

PROPERTIES OF SOLUTIONS

9

Partial molar properties, ideal and non-ideal solutions, standard states definition and choice, Gibbs-Duhem equation, excess properties of mixtures.

UNIT II

PHASE EQUILIBRIA

9

Criteria for equilibrium between phases in multi component non-reacting systems in terms of chemical potential and fugacity, application of phase rule, vapour-liquid equilibrium, phase diagrams for homogeneous systems and for systems with a miscibility gap, effect of temperature and pressure on azeotrope composition, liquid-liquid equilibrium, ternary liquid-liquid equilibrium.


UNIT III

CORRELATION AND PREDICTION OF PHASE EQUILIBRIA

9

Activity coefficient-composition models, thermodynamic consistency of phase equilibria, application of the correlation and prediction of phase equilibria in systems of engineering interest particularly to distillation and liquid extraction processes.

UNIT IV

CHEMICAL REACTION EQUILIBRIA

9

Definition of standard state, standard free energy change and reaction equilibrium constant, evaluation of reaction equilibrium constant, prediction of free energy data, equilibria in chemical reactors, calculation of equilibrium compositions for homogeneous chemical reactors, thermodynamic analysis of simultaneous reactions.

UNIT V

REFRIGERATION

9

Principles of refrigeration, methods of producing refrigeration, liquefaction process, co-efficient of performance, evaluation of the performance of vapour compression and gas refrigeration cycles.

TOTAL (L : 45, T : 15) : 60 PERIODS

OUTCOMES:
Students will be able to apply mass, energy and entropy balances to flow processes.

TEXT BOOKS:
1. Smith, J.M., VanNess, H.C., & Abbot M.C, “Introduction to Chemical Engineering Thermodynamics”, McGraw Hill VII Edition 2004.
2. Narayanan K.V “A Text Book of Chemical Engineering Thermodynamics” Prentice Hall of India Pvt. Ltd. 2001.

REFERENCES
1. Hougen, O.A., Watson, K.M., and Ragatz, R.A., “Chemical Process Principles Part II”, Thermodynamics, John Wiley, 1970.
2. Dodge, B.F., “Chemical Engineering Thermodynamics”, McGraw-Hill, 1960.
3. Sandler, S.I., “Chemical and Engineering Thermodynamics”, 2nd Edition, Wiley, 1989.

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