CY8292 - CHEMISTRY FOR TECHNOLOGISTS (Syllabus) 2017-regulation Anna University

CY8292

CHEMISTRY FOR TECHNOLOGISTS

 LPTC

3003

UNIT I

UNIT PROCESSES

9

Nitration, Sulphonation, Halogenation, Esterification, Amination, Saponification and Hydrogenation – Role of the above unit processes in such industries as petroleum, drugs, pharmaceuticals and organic synthesis.

UNIT II

REACTION MECHANISMS

9

Free radical, substitutions, electrophilic, addition, aromatic electrophilic substitutions, nucleophilic additions, condensation reactions, nucleophilic substitutions in aliphatic and aromatic compounds, cyclo-additions, rearrangements-Beckmann and Fries rearrangement reactions.


UNIT III

OILS, FATS, SOAPS & LUBRICANTS

9

Chemical constitution, Chemical analysis of oils and fats – acid, saponification and iodine values, Definitions, determinations and significance. Definition, mechanism of lubrication, preparation of petrolubes, desirable characteristics – viscosity, viscosity index, carbon residue, oxidation stability, flash and fire points, cloud and pour points, aniline point. Semisolid lubricant – greases, preparation of sodium, lithium, calcium and axle greases and uses, consistency test and drop point test. Solid lubricants – graphite and molybdenum disulphide.

UNIT IV

CHEMICALS AND AUXILIARIES

9

Preparation, properties and uses of bleaching powder, sodium hypochlorite, hydrogen peroxide, chlorine dioxide. Estimation of available chlorine in hypochlorite bleach liquor. Determination of strength of hydrogen peroxide.

UNIT V

COLORANTS

9

Theory of color and constitution: chromophore and auxochrome, classification of dyes based on application. Chemistry and synthesis of azo dye (Methyl red, Methyl orange and Congo red)

TOTAL : 45 PERIODS

TEXT BOOKS:
1. Dhara S. S., “A Text Book of Engineering Chemistry”, 12th Ed., S. Chand & Co. Ltd., New Delhi, 2016.
2. Jain. P.C. and Monica Jain, “Engineering Chemistry”, Dhanpet Rai & Sons, New Delhi, 2012.
3. Shikha Agarwal, “Engineering Chemistry-Fundamentals and Applications”, Cambridge University Press, Delhi, 2015.

REFERENCES:
1. W.L. McCabe, J.C. Smith and P. Harriot, Unit Operations of Chemical Engineering, 7th Edition, McGraw Hill Education, 2005.
2. B.K. Sharma, “Industrial chemistry”, Krishna Prakashan Media (P) Ltd, Meerut, 2011.
3. Shore J., “Colourants and Auxiliaries: Volume II Auxiliaries”, Wood head Publishing Ltd., 2002.
4. Shenai V. A., “Chemistry of Dyes and Principles of Dyeing”, Sevak Publications, Mumbai, 1995.
5. Trotman E. R., “Dyeing and Chemical Technology of Textile Fibres”, B.I Publishing Pvt. Ltd., New Delhi, 1994.

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