FD6404 - THERMODYNAMICS (Syllabus) 2013-regulation Anna University

FD6404 - THERMODYNAMICS (Syllabus) 2013-regulation Anna University

FD6404

THERMODYNAMICS

 LPTC

3003

UNIT I

THERMODYNAMIC LAW AND PROPERTIES OF FLUIDS

9

First Law of thermodynamics, a generalized balance equation and conserved quantities, Volumetric properties of fluids exhibiting non ideal behavior; residual properties; estimation of thermodynamic properties using equations of state; calculations involving actual property exchanges; Maxwell’s relations and applications.

UNIT II

SOLUTION THERMODYNAMICS

9

Partial molar properties; concepts of chemical potential and fugacity; ideal and non- ideal solutions; concepts and applications of excess properties of mixtures; activity coefficient; composition models; Gibbs Duhem equation.


UNIT III

PHASE EQUILIBRIA

9

Criteria for phase equilibria; VLE calculations for binary and multi component systems; liquid liquid equilibria and solid-solid equilibria.

UNIT IV

CHEMICAL REACTION EQUILIBRIA

9

Equilibrium criteria for homogeneous chemical reactions; evaluation of equilibrium constant; effect of temperature and pressure on equilibrium constant; calculation of equilibrium conversion and yields for single and multiple reactions.

UNIT V

THERMODYNAMIC DESCRIPTION OF MICROBIAL GROWTH AND PRODUCT FORMATION

9

Thermodynamics of microbial growth stoichiometry thermodynamics of maintenance, Calculation of the Operational Stoichiometry of a growth process at Different growth rates,Including Heat using the Herbert –Pirt Relation for Electron Donor, thermodynamics and stoichiometry of Product Formation

TOTAL : 45 PERIODS

TEXT BOOKS:
1. Smith J.M., Van Ness H.C., and Abbot M.M. “Introduction to Chemical Engineering Thermodynamics”, 6th Edition. Tata McGraw-Hill, 2003.
2. Narayanan K.V. “A Text Book of Chemical Engineering Thermodynamics”, PHI, 2003.
3. Christiana D. Smolke, “ The Metabolic Pathway Engineering Handbook Fundamentals”, CRC Press Taylor & Francis Group, 2010.

REFERENCE
1. Sandler S.I. “Chemical and Engineering Thermodynamics”, John Wiley,1989.

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