TC6303 - ORGANIC CHEMISTRY (Syllabus) 2013-regulation Anna University

TC6303	ORGANIC CHEMISTRY	LPTC

3003

OBJECTIVES:

To impart knowledge on various reaction mechanism, preparation of organic compounds and their properties. This will be a precursor for the study on Chemical Reaction Engineering.

UNIT I	ALIPHATIC HYDROCARBONS AND ALCOHOLS	9

Alkanes – General methods of preparation – Physical and chemical properties – Alkenes – General methods of preparation – Physical and chemical properties – Markovnikov’s rule – Peroxide effect – Bayer’s test – Alkynes – General methods of preparation and properties monohydric alcohols – Saytzeff rule – Methods of distinguishing the three classes of alcohols – Lucas test – Dichromate test.

UNIT II	ALDEHYDES, KETONES AND ACIDS	9

General methods of preparation – Physical and chemical properties – Aldol condensation – Clemmensen reduction – Wolf-Kishner reduction – Haloform reaction – Cannizzaro reaction – Reformatsky reaction – Wittig reaction – Saturated monocarbozylic acids – Methods of preparation – Physical and chemical properties – Hell-Volhard-Zelinsky reaction – Amino acids – Methods of preparation – Physical and chemical properties.

UNIT III	CARBOHYDRATES	9

Classification of carbohydrates – Monosaccharides – Reactions of glucose and fructose – Open chain and cyclic structures of glucose and fructose – Mutarotation – Epimerization – Killiani-Fisher synthesis – Ruff degradation – Conversion of aldoses to ketoses and ketoses to aldoses – Disaccharides – Properties and structure of sucrose – Polysaccharides – Properties and structure of starch and cellulose – Derivatives of cellulose – Carboxy methyl cellulose and gun cotton.

UNIT IV	AROMATIC HYDROCARBON, AMINE AND DIAZONIUM SALT	9

Benzene – Aromaticity – Huckel rule – General methods of preparation of benzene – Electrophilic substitution reactions – Directive effects of substituents – Aromatic amino compounds – General methods of preparation – Physical and chemical properties – Carbylamines reaction – Aryldiazonium salts – Preparation and synthetic applications.

UNIT V	DYES AND DYEING	9

Colour and constitution – Synthesis – Azodyes – Methyl orange – Methyl red and congo red – Triphenylmethane dyes – Malachite green – Para-rosaniline – Alizarin – Eosin – Introduction to natural and reactive dyes.

TOTAL : 45 PERIODS

OUTCOMES: At the end of this course, the student will be able to

• Identify what distinguishes a strong and weak nucleophile and recall the rules of reactions
• Analyzes a list of compounds and determines their reactivity.

TEXT BOOKS:

1. Morrison R.T. and Boyd R.N., “Organic chemistry”, 6th Edition, Prentice Hall of India (P) Ltd., 2003.
2. Arun Bahl and Bahl B.S., “Advanced Organic Chemistry”, 16th Edition, S.Chand and Company Ltd., 2002.

REFERENCES

1. March J., “March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure”, 5th Edition, John Wiley, 2001.
2. Finar I.L., “Organic chemistry” Vol-I, 6th Edition, Pearson Education, 2002.
3. Sharma B.K., “Industrial Chemistry”, 12th Edition, Goel Publishing house, 2001.