PE8491 - CHEMICAL ENGINEERING THERMODYNAMICS (Syllabus) 2017-regulation Anna University

PE8491 - CHEMICAL ENGINEERING THERMODYNAMICS (Syllabus) 2017-regulation Anna University

PE8491

CHEMICAL ENGINEERING THERMODYNAMICS

 LPTC

3003

OBJECTIVE:
• Students will learn PVT behaviour of fluids, laws of thermodynamics, thermodynamic property relations and their application to fluid flow, power generation and refrigeration processes.

UNIT I

9

Scope of thermodynamics, basic concepts and definitions, Equilibrium state and phase rule, Energy, Work, Temperature and Zeroth Law of Thermodynamics, reversible and irreversible process, Ideal gas- Equation of State involving ideal and real gas, Law of corresponding states, Compressibility chart, First Law of Thermodynamics and its consequences.

UNIT II

9

Joule’s experiment, internal energy, enthalpy, Application of first Law of Thermodynamics for Flow and non flow processes. Limitations of the first Law , statements of second Law of Thermodynamics and its Applications ,Heat Engine, Heat Pump/Refrigerator, Carnot cycle and Carnot theorem, Thermodynamic Temperature scale, Entropy , Clausius inequality, Third law of thermodynamics.


UNIT III

9

Refrigeration and liquefaction process, Thermodynamic Potentials, thermodynamic correlation, Maxwell relations, criteria for Equilibria and stability. Clapeyron equation

UNIT IV

9

Partial molar properties, ideal and non-ideal solutions, standard states definition and choice, Gibbs-Duhem equation, activity and property change of mixing, excess properties of mixtures.

UNIT V

9

Activity coefficient-composition models, thermodynamic consistency of phase equilibria, ChemicalReaction equilibria, Extent of reaction, equilibrium constant and standard free energy change

TOTAL : 45 PERIODS

OUTCOME:
• The course will help the students to know about engineering thermodynamics and understand the practical implications of thermodynamic law in engineering design.

TEXT BOOKS:
1. Sonntag, Borgnakke, Van Wylen, Fundamentals of Thermodynamics, 7th Edition, Wiley India, New Delhi, 2009.
2. Narayanan, K.V. A Textbook of Chemical Engineering Thermodynamics Prentice Hall India, 2004
3. Smith, van Ness and Abbott, “Chemical Engineering Thermodynamics”, 7th Edition, McGraw Hill, New York, 2005

REFERENCES:
1. S. I. Sandler, Chemical, Biochemical and Engineering Thermodynamics, Wiley New York, 2006
2. Y V C Rao, “Chemical Engineering Thermodynamics”, Universities Press, Hyderabad 2005.
3. Pradeep ahuja,” Chemical Engineering Thermodynamics”, PHI Learning Ltd (2009).
4. GopinathHalder,” Introduction to Chemical Engineering Thermodynamics”, PHI Learning Ltd (2009).

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