## CH3401 Syllabus - Chemical Engineering Thermodynamics - I - 2021 Regulation Anna University

CH3401

CHEMICAL ENGINEERING THERMODYNAMICS - I

LTPC

3003

COURSE OBJECTIVES: The course is aimed to enable the students to
• Learn PVT behaviour of fluids, laws of thermodynamics, thermodynamic property relations and their application to fluid flow, power generation and refrigeration processes.

UNIT I

9

Terminologies of thermodynamics, the variables and quantities of thermodynamics, characteristics of systems and processes, energy classifications, point and path functions, energy in transition work and heat. Zeroth law; temperature scales

UNIT II

9

The first law of thermodynamics, statements of first law for the flow and non-flow processes. PVT behaviour of fluids; Mathematical representation of PVT behaviour; generalized compressibility factor correlation; generalized equations of state

UNIT III

9

Joule’s experiment, energy balance for closed systems, mass and energy balance for open systems, Statements of the second law of thermodynamics, heat engine and refrigerator, Carnot cycle and Carnot theorems, thermodynamic temperature scale, entropy and its calculation, second law of thermodynamics for a control volume, Third law of thermodynamics, entropy from a microscopic point of view.

UNIT IV

9

Thermodynamic properties – internal energy, enthalpy, Helmholtz free energy, Gibbs free energy; thermodynamic property relations – Maxwell relations – partial derivatives and Jacobian method; residual properties; thermodynamic property tables and diagrams.

UNIT V

9

Thermodynamic aspects of compression, expansion processes and duct flow of compressible fluids, steam power plant.

TOTAL: 45 PERIODS

COURSE OUTCOMES: On the completion of the course students are expected to
CO1: Understand the fundamental concepts of thermodynamics and its related functions
CO2: Relate PVT behaviour of fluids and understand the real gas behavior
CO3: Apply second law and analyse the feasibility of system/devices
CO4: Analyse the thermodynamic property relations and their application to fluid flow
CO5: Develop the significance of thermodynamic potentials and their use in the analysis of processes
CO6: Formulate thermodynamic formulations and the working of compressors and expanders

TEXT BOOKS:
1. Smith J.M., VanNess,H.C., & Abbot M.C,” Introduction to Chemical Engineering Thermodynamics”,McGraw Hill VII Edition 2009
2. Kyle B.G.,”Chemical and Process Thermodynamics”, Pearson International third Edition.
3. Rao Y.V.C.,”Chemical Engineering Thermodynamics”Universities Press, 2005
4. Koretsky.,Engineering and Chemical thermodynamics,Wiley,2011

REFERENCES:
1. Sandler,S.I.,”Chemical and Engineering Thermodynamics”,IV Edition,Wiley,2006.
2. Narayanan K.V”A Text Book of Chemical Engineering Thermodynamics”Prentice Hall of India Pvt.Ltd,2 nd edition,2013.
3. Kevin Douglas, Fundamentals of Chemical Engineering Thermodynamics, Timothy Anderson,2015