PE3451 Syllabus - Chemical Engineering Thermodynamics - 2021 Regulation Anna University
PE3451 Syllabus - Chemical Engineering Thermodynamics - 2021 Regulation Anna University
PE3451 | CHEMICAL ENGINEERING THERMODYNAMICS | LPTC |
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3003
COURSE OBJECTIVES:
• Students will learn PVT behaviour of fluids, laws of thermodynamics,
thermodynamic property relations and their application to fluid flow,
power generation and refrigeration processes.
UNIT I | PVT RELATIONS AND FIRST LAW OF THERMODYNAMICS | 9 |
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Scope of thermodynamics, basic concepts and definitions, Equilibrium state
and phase rule, Energy, Work, Temperature and Zeroth Law of
Thermodynamics, reversible and irreversible process, Ideal gas- Equation
of State involving ideal and real gas, Law of corresponding states,
Compressibility chart, First Law of Thermodynamics and its consequences.
UNIT II | SECOND LAW AND THERMODYNAMIC CORRELATIONS | 9 |
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Application of first Law of Thermodynamics for Flow and non-flow
processes. Limitations of the first Law, statements of second Law of
Thermodynamics, Thermodynamic Temperature scale, Entropy, Third law of
thermodynamics. Thermodynamic Potentials, thermodynamic correlation,
Maxwell relations. Clapeyron equation.
UNIT III | SOLUTION THERMODYNAMICS | 9 |
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Partial molar properties, ideal and non-ideal solutions, standard states
definition and choice, Gibbs-Duhem equation, activity and property change
of mixing, excess properties of mixtures. Activity coefficient-composition
models.
UNIT IV | PHASE EQUILIBRIA | 9 |
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Phase equilibrium in ideal solution, excess Gibbs free energy models,
Henry’s law, fugacity, Vapor-Liquid Equilibrium at low, moderate and high
pressures; bubble and dew point calculation, thermodynamic consistency
test of VLE data, Phase diagrams for homogeneous systems and for systems
with a miscibility gap, effect of temperature and pressure on azeotrope
composition, liquid-liquid equilibrium.
UNIT V | REACTION EQUILIBRIA | 9 |
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Chemical Reaction Equilibrium of single and multiple reactions, Standard
Gibbs free change, equilibrium constant-effect of temperature; homogeneous
gas and liquid phase reactions.
TOTAL: 45 PERIODS
COURSE OUTCOMES:
1. Understand the fundamentals of system of units, apply ideal gas law to
solve problems in pure components and mixtures.
2. Apply stoichiometric principles to solve problems and write material balance for different process equipments.
3. Understand and apply basics of humidity to solve problems in humidification and other processes.
4. Understand and apply the basics of energy balance concepts to solve to different chemical processes.
5. Understand the basics of fuels and combustion, to solve problems on combustion of various fuels and also to find excess air.
6. Apply the above knowledge to process flow sheeting in industries.
2. Apply stoichiometric principles to solve problems and write material balance for different process equipments.
3. Understand and apply basics of humidity to solve problems in humidification and other processes.
4. Understand and apply the basics of energy balance concepts to solve to different chemical processes.
5. Understand the basics of fuels and combustion, to solve problems on combustion of various fuels and also to find excess air.
6. Apply the above knowledge to process flow sheeting in industries.
TEXT BOOKS:
1. Sonntag, Borgnakke, Van Wylen, Fundamentals of Thermodynamics, 7th
Edition, Wiley India, New Delhi, 2009.
2. Narayanan, K.V. A Textbook of Chemical Engineering Thermodynamics Prentice Hall India, 2004.
3. Smith, van Ness and Abbott, “Chemical Engineering Thermodynamics”, 7th Edition, McGraw Hill, New York, 2005.
2. Narayanan, K.V. A Textbook of Chemical Engineering Thermodynamics Prentice Hall India, 2004.
3. Smith, van Ness and Abbott, “Chemical Engineering Thermodynamics”, 7th Edition, McGraw Hill, New York, 2005.
REFERENCES:
1. S. I. Sandler, Chemical, Biochemical and Engineering Thermodynamics,
Wiley New York, 2006.
2. Y V C Rao, “Chemical Engineering Thermodynamics”, Universities Press, Hyderabad 2005.
3. Pradeep Ahuja,” Chemical Engineering Thermodynamics”, PHI Learning Ltd (2009).
4. Gopinath Halder,” Introduction to Chemical Engineering Thermodynamics”, PHI Learning Ltd (2009).
2. Y V C Rao, “Chemical Engineering Thermodynamics”, Universities Press, Hyderabad 2005.
3. Pradeep Ahuja,” Chemical Engineering Thermodynamics”, PHI Learning Ltd (2009).
4. Gopinath Halder,” Introduction to Chemical Engineering Thermodynamics”, PHI Learning Ltd (2009).
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